A novel polymeric silver(I) complex with a one-dimensional chain structure

Weiping Su; Rong Cao; Maochun Hong; Wing Tak Wong; Jiaxi Lu

doi:10.1016/S1387-7003(99)00058-1

A novel polymeric silver(I) complex with a one-dimensional chain structure

Weiping Su, Rong Cao, Maochun Hong, Wing Tak Wong, Jiaxi Lu

Research output: Journal article publication › Journal article › Academic research › peer-review

49 Citations (Scopus)

Abstract

The polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3)4(μ2-SC4N2H3)2]nhas been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.

Original language	English
Pages (from-to)	241-243
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	6
DOIs	https://doi.org/10.1016/S1387-7003(99)00058-1
Publication status	Published - 1 Jun 1999
Externally published	Yes

Keywords

Crystal structures
One-dimensional chain
Silver(I) complexes
Thiolate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/S1387-7003(99)00058-1

Cite this

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title = "A novel polymeric silver(I) complex with a one-dimensional chain structure",

abstract = "The polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3)4(μ2-SC4N2H3)2]nhas been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.",

keywords = "Crystal structures, One-dimensional chain, Silver(I) complexes, Thiolate complexes",

author = "Weiping Su and Rong Cao and Maochun Hong and Wong, {Wing Tak} and Jiaxi Lu",

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doi = "10.1016/S1387-7003(99)00058-1",

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T1 - A novel polymeric silver(I) complex with a one-dimensional chain structure

AU - Su, Weiping

AU - Cao, Rong

AU - Hong, Maochun

AU - Wong, Wing Tak

AU - Lu, Jiaxi

PY - 1999/6/1

Y1 - 1999/6/1

N2 - The polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3)4(μ2-SC4N2H3)2]nhas been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.

AB - The polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3)4(μ2-SC4N2H3)2]nhas been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.

KW - Crystal structures

KW - One-dimensional chain

KW - Silver(I) complexes

KW - Thiolate complexes

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U2 - 10.1016/S1387-7003(99)00058-1

DO - 10.1016/S1387-7003(99)00058-1

M3 - Journal article

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VL - 2

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EP - 243

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

A novel polymeric silver(I) complex with a one-dimensional chain structure

Abstract

Keywords

ASJC Scopus subject areas

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