A novel polymeric silver(I) complex with a one-dimensional chain structure

Weiping Su, Rong Cao, Maochun Hong, Wing Tak Wong, Jiaxi Lu

Research output: Journal article publicationJournal articleAcademic researchpeer-review

49 Citations (Scopus)

Abstract

The polymeric silver(I)-thiolate complex [Ag6(μ3-SC4N2H3)4(μ2-SC4N2H3)2]nhas been prepared from the assembly reaction of AgSCN and sodium pyrimidine-2-thiolate in DMF. X-ray diffraction analyses show that the complex exhibits a one-dimensional chain structure with the metal atom core arranged in distorted tetrahedra sharing apexes. The pyrimidime-2-thiolate ligands in the chain act as both bridging and chelating ligands linking either two- or three-silver(I) centers. The coordination environment of each Ag(I) in the complex is either a distorted tetrahedron of S3N or a triangle of S2N.
Original languageEnglish
Pages (from-to)241-243
Number of pages3
JournalInorganic Chemistry Communications
Volume2
Issue number6
DOIs
Publication statusPublished - 1 Jun 1999
Externally publishedYes

Keywords

  • Crystal structures
  • One-dimensional chain
  • Silver(I) complexes
  • Thiolate complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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