A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me3tacn) for organic oxidation

Wing Chi Cheng; Wing Yiu Yu; Kung Kai Cheung; Chi Ming Che

doi:10.1039/C39940001063

A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me₃tacn) for organic oxidation

Wing Chi Cheng
, Wing Yiu Yu
, Kung Kai Cheung
, Chi Ming Che

Research output: Journal article publication › Journal article › Academic research › peer-review

61 Citations (Scopus)

Abstract

The X-ray structure of [Ru(Me3tacn)O2(CF 3CO2)]+ shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Å and 118.3(4)°respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.

Original language	English
Pages (from-to)	1063-1064
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39940001063
Publication status	Published - 1 Dec 1994
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39940001063

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title = "A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me3tacn) for organic oxidation",

abstract = "The X-ray structure of [Ru(Me3tacn)O2(CF 3CO2)]+ shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) {\AA} and 118.3(4)°respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.",

author = "Cheng, \{Wing Chi\} and Yu, \{Wing Yiu\} and Cheung, \{Kung Kai\} and Che, \{Chi Ming\}",

year = "1994",

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doi = "10.1039/C39940001063",

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A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me₃tacn) for organic oxidation. / Cheng, Wing Chi; Yu, Wing Yiu; Cheung, Kung Kai et al.
In: Journal of the Chemical Society D: Chemical Communications, No. 9, 01.12.1994, p. 1063-1064.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me3tacn) for organic oxidation

AU - Cheng, Wing Chi

AU - Yu, Wing Yiu

AU - Cheung, Kung Kai

AU - Che, Chi Ming

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The X-ray structure of [Ru(Me3tacn)O2(CF 3CO2)]+ shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Å and 118.3(4)°respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.

AB - The X-ray structure of [Ru(Me3tacn)O2(CF 3CO2)]+ shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Å and 118.3(4)°respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.

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U2 - 10.1039/C39940001063

DO - 10.1039/C39940001063

M3 - Journal article

SN - 0022-4936

SP - 1063

EP - 1064

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 9

ER -

A novel cis-dioxoruthenium(VI) complex of N,N′,N′-trimethyl-1, 4,7-triazacyclononane (Me₃tacn) for organic oxidation

Abstract

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