A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate

Ye Gao Yin; Kung Kai Cheung; Wing Tak Wong

doi:10.1016/S0277-5387(97)00035-1

A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate

Ye Gao Yin, Kung Kai Cheung, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

3 Citations (Scopus)

Abstract

The supramolecular host molecule N,N′,N″-tris(ruthenocenylinethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N-H: 0.71 Å). Cyclic voltammetric measurement displays an irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuIIto RuIIIof the appended metallocenes.

Original language	English
Pages (from-to)	2889-2891
Number of pages	3
Journal	Polyhedron
Volume	16
Issue number	16
DOIs	https://doi.org/10.1016/S0277-5387(97)00035-1
Publication status	Published - 1 Jan 1997
Externally published	Yes

Keywords

Molecular structure
Protonation
Ruthenocene
Supramolecular host
Tacn

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/S0277-5387(97)00035-1

Cite this

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title = "A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate",

abstract = "The supramolecular host molecule N,N′,N″-tris(ruthenocenylinethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N-H: 0.71 {\AA}). Cyclic voltammetric measurement displays an irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuIIto RuIIIof the appended metallocenes.",

keywords = "Molecular structure, Protonation, Ruthenocene, Supramolecular host, Tacn",

author = "Yin, {Ye Gao} and Cheung, {Kung Kai} and Wong, {Wing Tak}",

year = "1997",

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doi = "10.1016/S0277-5387(97)00035-1",

language = "English",

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A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate. / Yin, Ye Gao; Cheung, Kung Kai; Wong, Wing Tak.
In: Polyhedron, Vol. 16, No. 16, 01.01.1997, p. 2889-2891.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate

AU - Yin, Ye Gao

AU - Cheung, Kung Kai

AU - Wong, Wing Tak

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The supramolecular host molecule N,N′,N″-tris(ruthenocenylinethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N-H: 0.71 Å). Cyclic voltammetric measurement displays an irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuIIto RuIIIof the appended metallocenes.

AB - The supramolecular host molecule N,N′,N″-tris(ruthenocenylinethyl)-1,4,7-triazacyclononane perchlorate [LH] ClO4was prepared and its molecular structure was determined by single crystal X-ray analysis. The guest proton was localized on one of the aza atoms of the macrocycle (N-H: 0.71 Å). Cyclic voltammetric measurement displays an irreversible oxidation wave at 0.84 V and is attributable to the oxidation of RuIIto RuIIIof the appended metallocenes.

KW - Molecular structure

KW - Protonation

KW - Ruthenocene

KW - Supramolecular host

KW - Tacn

UR - http://www.scopus.com/inward/record.url?scp=0039462128&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(97)00035-1

DO - 10.1016/S0277-5387(97)00035-1

M3 - Journal article

SN - 0277-5387

VL - 16

SP - 2889

EP - 2891

JO - Polyhedron

JF - Polyhedron

IS - 16

ER -

A new supramolecular macrocyclic host incorporated with ruthenocene ionosphere-synthesis and X-ray crystal structure of N,N′,N″-tris(ruthenocenylmethyl)-1,4,7-triazacyclononane perchlorate

Abstract

Keywords

ASJC Scopus subject areas

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