A near-infrared-fluorescent chemodosimeter for mercuric ion based on an expanded porphyrin

Xun Jin Zhu, Shi Tao Fu, Wai Kwok Wong, Jian Ping Guo, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

225 Citations (Scopus)

Abstract

(Chemical Equation Presented) Running rings around mercuric ions: A [26]hexaphyrin(1.1.1.1.1.0), comprising an α,α′-bipyrrole unit and four pyrrolic and five pentafluorophenyl rings, was prepared and characterized by X-ray crystallography (see picture; N blue, F green, C black). The expanded porphyrin displays near-infrared luminescence above 900 nm and may serve as a highly sensitive and selective chemodosimeter for Hg2+ ions. KGaA.
Original languageEnglish
Pages (from-to)3150-3154
Number of pages5
JournalAngewandte Chemie - International Edition
Volume45
Issue number19
DOIs
Publication statusPublished - 5 May 2006
Externally publishedYes

Keywords

  • Fluorescence
  • Mercury
  • Nitrogen heterocycles
  • Porphyrinoids
  • Sensors

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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