A "molecular pivot-hinge" based on the pH-regulated intramolecular switching of Pt-Pt and π-π interactions

Chi Kin Koo, Benny Lam, Sze Kar Leung, Michael Hon Wah Lam, Wai Yeung Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

84 Citations (Scopus)

Abstract

The binuclear cycloplatinated complex {[Pt(L)]2(μ-dppm)}2+ (1), where HL is a new cyclometalating ligand 2-phenyl-6-(1H-pyrazol-3-yl)pyridine, is found to behave as a molecular pivot-hinge in which the closing and opening of the hinge is effected by the reversible formation and cleavage of the Pt-Pt d8-d8 interaction and the intramolecular π-π interaction mediated by the protonation/deprotonation of the 1-pyrazolyl-NH on the cyclometalating ligand L.
Original languageEnglish
Pages (from-to)16434-16435
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number51
DOIs
Publication statusPublished - 27 Dec 2006
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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