TY - JOUR
T1 - A High-Capacity, Long-Cycling All-Solid-State Lithium Battery Enabled by Integrated Cathode/Ultrathin Solid Electrolyte
AU - Lin, Yanke
AU - Wu, Maochun
AU - Sun, Jing
AU - Zhang, Leicheng
AU - Jian, Qinping
AU - Zhao, Tianshou
N1 - Funding Information:
The work described in this paper was supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China (Project NO. R6005‐20).
Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/9/16
Y1 - 2021/9/16
N2 - Current all-solid-state lithium battery (ASSLB) manufacturing typically involves laborious fabrication and assembly of individual electrodes and solid electrolyte, which inevitably result in large interfacial resistances. Moreover, due to the unfavorable mechanical strength, most solid electrolytes are fabricated to be overly thick and are incapable of retarding lithium dendrite formation. These factors limit the attainable energy density and cyclability of ASSLBs. Here, a novel integrated cathode/solid electrolyte for scalable ASSLB manufacturing is reported by directly fabricating an ultrathin yet robust fiber network reinforced solid electrolyte on the cathode. The integrated design allows continuous ion conduction at both the interface and the entire cathode, thereby considerably reducing interfacial resistance and enabling higher cathode loading. Meanwhile, the strong fiber network endows the solid electrolyte with an ultrasmall thickness and superior dendrite suppression capability. As a result, the newly-developed Li/LiFePO4 ASSLB achieves a high capacity of 155.2 mAh g–1 at 0.5 C and 45 °C with capacity retention of 84.3% after 500 cycles. Even with a cathode loading of 13 mg cm–2, the battery still delivers a capacity of 124.1 mAh g–1. Additionally, a pouch cell with this integrated design displays good electrochemical performance and safety, showing great promise for practical applications.
AB - Current all-solid-state lithium battery (ASSLB) manufacturing typically involves laborious fabrication and assembly of individual electrodes and solid electrolyte, which inevitably result in large interfacial resistances. Moreover, due to the unfavorable mechanical strength, most solid electrolytes are fabricated to be overly thick and are incapable of retarding lithium dendrite formation. These factors limit the attainable energy density and cyclability of ASSLBs. Here, a novel integrated cathode/solid electrolyte for scalable ASSLB manufacturing is reported by directly fabricating an ultrathin yet robust fiber network reinforced solid electrolyte on the cathode. The integrated design allows continuous ion conduction at both the interface and the entire cathode, thereby considerably reducing interfacial resistance and enabling higher cathode loading. Meanwhile, the strong fiber network endows the solid electrolyte with an ultrasmall thickness and superior dendrite suppression capability. As a result, the newly-developed Li/LiFePO4 ASSLB achieves a high capacity of 155.2 mAh g–1 at 0.5 C and 45 °C with capacity retention of 84.3% after 500 cycles. Even with a cathode loading of 13 mg cm–2, the battery still delivers a capacity of 124.1 mAh g–1. Additionally, a pouch cell with this integrated design displays good electrochemical performance and safety, showing great promise for practical applications.
KW - ASSLBs
KW - high cathode loading
KW - interfaces
KW - scalable manufacturing
KW - ultrathin solid electrolytes
UR - http://www.scopus.com/inward/record.url?scp=85111354914&partnerID=8YFLogxK
U2 - 10.1002/aenm.202101612
DO - 10.1002/aenm.202101612
M3 - Journal article
AN - SCOPUS:85111354914
SN - 1614-6832
VL - 11
JO - Advanced Energy Materials
JF - Advanced Energy Materials
IS - 35
M1 - 2101612
ER -