A general palladium-catalyzed Suzuki-Miyaura coupling of aryl mesylates

Chau Ming So; Chak Po Lau; Fuk Yee Kwong

doi:10.1002/anie.200803193

A general palladium-catalyzed Suzuki-Miyaura coupling of aryl mesylates

Chau Ming So, Chak Po Lau, Fuk Yee Kwong

Research output: Journal article publication › Journal article › Academic research › peer-review

168 Citations (Scopus)

Abstract

(Chemical Equation Presented) Catalyze this! The first palladium-catalyzed Suzuki-Miyaura coupling of unactivated aryl mesylates is reported, with not only arylboronic acids, but also other organoboron nucleophiles (see picture; Z=B(OH)2, BF3K, BPin). The reaction conditions are compatible with various common functional groups (R1=alkyl, OMe, CHO, CO, CN, CO2R′, heteroaryl). KGaA.

Original language	English
Pages (from-to)	8059-8063
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	42
DOIs	https://doi.org/10.1002/anie.200803193
Publication status	Published - 6 Oct 2008

Keywords

Cross-coupling
Homogeneous catalysis
Mesylates
Palladium
Phosphanes

ASJC Scopus subject areas

Catalysis
General Chemistry

More information

10.1002/anie.200803193

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abstract = "(Chemical Equation Presented) Catalyze this! The first palladium-catalyzed Suzuki-Miyaura coupling of unactivated aryl mesylates is reported, with not only arylboronic acids, but also other organoboron nucleophiles (see picture; Z=B(OH)2, BF3K, BPin). The reaction conditions are compatible with various common functional groups (R1=alkyl, OMe, CHO, CO, CN, CO2R′, heteroaryl). KGaA.",

keywords = "Cross-coupling, Homogeneous catalysis, Mesylates, Palladium, Phosphanes",

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AB - (Chemical Equation Presented) Catalyze this! The first palladium-catalyzed Suzuki-Miyaura coupling of unactivated aryl mesylates is reported, with not only arylboronic acids, but also other organoboron nucleophiles (see picture; Z=B(OH)2, BF3K, BPin). The reaction conditions are compatible with various common functional groups (R1=alkyl, OMe, CHO, CO, CN, CO2R′, heteroaryl). KGaA.

KW - Cross-coupling

KW - Homogeneous catalysis

KW - Mesylates

KW - Palladium

KW - Phosphanes

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JO - Angewandte Chemie - International Edition

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A general palladium-catalyzed Suzuki-Miyaura coupling of aryl mesylates

Abstract

Keywords

ASJC Scopus subject areas

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