A double chain coordination polymer: {[Zn(H2O) 6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H 2O]·4H2O}n

Yang Yi Yang; Lap Szeto; Wing Tak Wong

doi:10.1002/aoc.559

A double chain coordination polymer: {[Zn(H2O) 6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H 2O]·4H2O}n

Yang Yi Yang, Lap Szeto, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

10 Citations (Scopus)

Abstract

The double-chain coordination polymer, {[Zn(H2O) 6][Zn(bbtc)H2O]·4H2O}n (bbtc = 3,3′,4,4′-benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal.

Original language	English
Pages (from-to)	958-959
Number of pages	2
Journal	Applied Organometallic Chemistry
Volume	17
Issue number	12
DOIs	https://doi.org/10.1002/aoc.559
Publication status	Published - 1 Dec 2003
Externally published	Yes

Keywords

Benzophenonetetracarboxylic acid
Coordination polymer
Crystal structure
Zinc complex

ASJC Scopus subject areas

Chemistry (miscellaneous)
Inorganic Chemistry

More information

10.1002/aoc.559

Cite this

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title = "A double chain coordination polymer: {[Zn(H2O) 6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H 2O]·4H2O}n",

abstract = "The double-chain coordination polymer, {[Zn(H2O) 6][Zn(bbtc)H2O]·4H2O}n (bbtc = 3,3′,4,4′-benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal.",

keywords = "Benzophenonetetracarboxylic acid, Coordination polymer, Crystal structure, Zinc complex",

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year = "2003",

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doi = "10.1002/aoc.559",

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T1 - A double chain coordination polymer: {[Zn(H2O) 6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H 2O]·4H2O}n

AU - Yang, Yang Yi

AU - Szeto, Lap

AU - Wong, Wing Tak

PY - 2003/12/1

Y1 - 2003/12/1

N2 - The double-chain coordination polymer, {[Zn(H2O) 6][Zn(bbtc)H2O]·4H2O}n (bbtc = 3,3′,4,4′-benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal.

AB - The double-chain coordination polymer, {[Zn(H2O) 6][Zn(bbtc)H2O]·4H2O}n (bbtc = 3,3′,4,4′-benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three bbtc ligands, and a water molecule, forming a geometry intermediate between square-pyramidal and trigonal bipyramidal.

KW - Benzophenonetetracarboxylic acid

KW - Coordination polymer

KW - Crystal structure

KW - Zinc complex

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U2 - 10.1002/aoc.559

DO - 10.1002/aoc.559

M3 - Journal article

SN - 0268-2605

VL - 17

SP - 958

EP - 959

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 12

ER -

A double chain coordination polymer: {[Zn(H2O) 6][Zn(3,3′,4,4′-benzophenonetetracarboxylate)H 2O]·4H2O}n

Abstract

Keywords

ASJC Scopus subject areas

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