TY - JOUR
T1 - A chiral bicyclo[2.2.2]octa-2,5-diene ligand substituted with the ferrocenyl group and its use for rhodium-catalyzed asymmetric 1,4-addition reactions
AU - Zhou, Bo
AU - So, Chau Ming
AU - Lu, Yixin
AU - Hayashi, Tamio
PY - 2015/1/1
Y1 - 2015/1/1
N2 - This journal is A chiral diene, (R,R)-Fc,Ph-bod, which bears the ferrocenyl (Fc) group and the phenyl (Ph) group on the bicyclo[2.2.2]octa-2,5-diene skeleton, has been synthesized, and its rhodium complex was examined as a catalyst for the asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated ketones. Its enantioselectivity was generally higher than that observed with (R,R)-Ph-bod, which is C2symmetric with two phenyl groups.
AB - This journal is A chiral diene, (R,R)-Fc,Ph-bod, which bears the ferrocenyl (Fc) group and the phenyl (Ph) group on the bicyclo[2.2.2]octa-2,5-diene skeleton, has been synthesized, and its rhodium complex was examined as a catalyst for the asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated ketones. Its enantioselectivity was generally higher than that observed with (R,R)-Ph-bod, which is C2symmetric with two phenyl groups.
UR - http://www.scopus.com/inward/record.url?scp=84937413938&partnerID=8YFLogxK
U2 - 10.1039/c4qo00292j
DO - 10.1039/c4qo00292j
M3 - Journal article
SN - 2052-4110
VL - 2
SP - 127
EP - 132
JO - Organic Chemistry Frontiers
JF - Organic Chemistry Frontiers
IS - 2
ER -