8-Quinolinolato complexes of ruthenium(II) and (III)

Chi Fai Leung, Chun Yuen Wong, Chi Chiu Ko, Man Chong Yuen, Wing Tak Wong, Wai Yeung Wong, Tai Chu Lau

Research output: Journal article publicationJournal articleAcademic researchpeer-review

10 Citations (Scopus)

Abstract

Reduction of RuQ3(1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various π-acceptor ligands in ethanol affords RuQ2L2(L2= (dimethylsulfoxide)2(2); (4-picoline)2(3); N,N′-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis,trans (6a) and trans,cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography.
Original languageEnglish
Pages (from-to)1149-1157
Number of pages9
JournalInorganica Chimica Acta
Volume362
Issue number4
DOIs
Publication statusPublished - 2 Mar 2009
Externally publishedYes

Keywords

  • 8-Quinolinolate
  • Alkene
  • Nitrogen ligands
  • Ruthenium

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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