2D graphdiyne loading ruthenium atoms for high efficiency water splitting

Huidi Yu; Lan Hui; Yurui Xue; Yuxin Liu; Yan Fang; Chengyu Xing; Chao Zhang; Danyan Zhang; Xi Chen; Yuncheng Du; Zhongqiang Wang; Yang Gao; Bolong Huang; Yuliang Li

doi:10.1016/j.nanoen.2020.104667

2D graphdiyne loading ruthenium atoms for high efficiency water splitting

Huidi Yu, Lan Hui, Yurui Xue, Yuxin Liu, Yan Fang, Chengyu Xing, Chao Zhang, Danyan Zhang, Xi Chen, Yuncheng Du, Zhongqiang Wang, Yang Gao, Bolong Huang (Corresponding Author), Yuliang Li

Research output: Journal article publication › Journal article › Academic research › peer-review

113 Citations (Scopus)

Abstract

The theoretical simulation indicates that the strong coupling between the Ru atoms and neighboring C atoms in GDY makes the Ru to be a unique electron-mediating-vehicle (EMV) for fast reversible redox-switching endowing the catalyst with excellent catalytic performances. Our experimental study is fully in accordance with the theoretical simulation, which shows that the high-activity and ultra-high selectivity of the Ru atomic catalyst. For example, Ru/GDY can deliver 10 mA cm⁻² at a low overpotential of 44 mV and exhibits a very small Tafel slope of 30 mV dec⁻¹, comparable to commercial Pt/C, in hydrogen evolution reaction (HER) in acidic conditions. We also found that Ru/GDY has higher catalytic activity and stability for oxygen evolution reaction (OER) than RuO₂ in 0.5 M H₂SO₄ solutions.

Original language	English
Article number	104667
Journal	Nano Energy
Volume	72
DOIs	https://doi.org/10.1016/j.nanoen.2020.104667
Publication status	Published - Jun 2020

Keywords

Acidic oxygen evolution reaction
Atom catalyst
Graphdiyne
Hydrogen production
Water splitting

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
General Materials Science
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.nanoen.2020.104667

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@article{8249b59cfe5e4c8f8afca13c836f2d48,

title = "2D graphdiyne loading ruthenium atoms for high efficiency water splitting",

abstract = "The theoretical simulation indicates that the strong coupling between the Ru atoms and neighboring C atoms in GDY makes the Ru to be a unique electron-mediating-vehicle (EMV) for fast reversible redox-switching endowing the catalyst with excellent catalytic performances. Our experimental study is fully in accordance with the theoretical simulation, which shows that the high-activity and ultra-high selectivity of the Ru atomic catalyst. For example, Ru/GDY can deliver 10 mA cm−2 at a low overpotential of 44 mV and exhibits a very small Tafel slope of 30 mV dec−1, comparable to commercial Pt/C, in hydrogen evolution reaction (HER) in acidic conditions. We also found that Ru/GDY has higher catalytic activity and stability for oxygen evolution reaction (OER) than RuO2 in 0.5 M H2SO4 solutions.",

keywords = "Acidic oxygen evolution reaction, Atom catalyst, Graphdiyne, Hydrogen production, Water splitting",

author = "Huidi Yu and Lan Hui and Yurui Xue and Yuxin Liu and Yan Fang and Chengyu Xing and Chao Zhang and Danyan Zhang and Xi Chen and Yuncheng Du and Zhongqiang Wang and Yang Gao and Bolong Huang and Yuliang Li",

year = "2020",

month = jun,

doi = "10.1016/j.nanoen.2020.104667",

language = "English",

volume = "72",

journal = "Nano Energy",

issn = "2211-2855",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - 2D graphdiyne loading ruthenium atoms for high efficiency water splitting

AU - Yu, Huidi

AU - Hui, Lan

AU - Xue, Yurui

AU - Liu, Yuxin

AU - Fang, Yan

AU - Xing, Chengyu

AU - Zhang, Chao

AU - Zhang, Danyan

AU - Chen, Xi

AU - Du, Yuncheng

AU - Wang, Zhongqiang

AU - Gao, Yang

AU - Huang, Bolong

AU - Li, Yuliang

PY - 2020/6

Y1 - 2020/6

N2 - The theoretical simulation indicates that the strong coupling between the Ru atoms and neighboring C atoms in GDY makes the Ru to be a unique electron-mediating-vehicle (EMV) for fast reversible redox-switching endowing the catalyst with excellent catalytic performances. Our experimental study is fully in accordance with the theoretical simulation, which shows that the high-activity and ultra-high selectivity of the Ru atomic catalyst. For example, Ru/GDY can deliver 10 mA cm−2 at a low overpotential of 44 mV and exhibits a very small Tafel slope of 30 mV dec−1, comparable to commercial Pt/C, in hydrogen evolution reaction (HER) in acidic conditions. We also found that Ru/GDY has higher catalytic activity and stability for oxygen evolution reaction (OER) than RuO2 in 0.5 M H2SO4 solutions.

AB - The theoretical simulation indicates that the strong coupling between the Ru atoms and neighboring C atoms in GDY makes the Ru to be a unique electron-mediating-vehicle (EMV) for fast reversible redox-switching endowing the catalyst with excellent catalytic performances. Our experimental study is fully in accordance with the theoretical simulation, which shows that the high-activity and ultra-high selectivity of the Ru atomic catalyst. For example, Ru/GDY can deliver 10 mA cm−2 at a low overpotential of 44 mV and exhibits a very small Tafel slope of 30 mV dec−1, comparable to commercial Pt/C, in hydrogen evolution reaction (HER) in acidic conditions. We also found that Ru/GDY has higher catalytic activity and stability for oxygen evolution reaction (OER) than RuO2 in 0.5 M H2SO4 solutions.

KW - Acidic oxygen evolution reaction

KW - Atom catalyst

KW - Graphdiyne

KW - Hydrogen production

KW - Water splitting

UR - http://www.scopus.com/inward/record.url?scp=85081588142&partnerID=8YFLogxK

U2 - 10.1016/j.nanoen.2020.104667

DO - 10.1016/j.nanoen.2020.104667

M3 - Journal article

AN - SCOPUS:85081588142

SN - 2211-2855

VL - 72

JO - Nano Energy

JF - Nano Energy

M1 - 104667

ER -

2D graphdiyne loading ruthenium atoms for high efficiency water splitting

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

More information

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