1D metal-dithiolene wires as a new class of bi-functional oxygen reduction and evolution single-atom electrocatalysts

Qingming Deng, Jin Han, Jiong Zhao, Guibin Chen, Tejs Vegge, Heine Anton Hansen

Research output: Journal article publicationJournal articleAcademic researchpeer-review

1 Citation (Scopus)

Abstract

Discovering low-cost, durable and highly active electrocatalysts with reduced use of precious platinum group metals (PGM) as catalysts for the hydrogen evolution reaction (HER), the oxygen reduction reaction (ORR), and the oxygen evolution reaction (OER) is a key step for large-scale adaptation of fuel cells, electrolyzers, and metal-air batteries. Here we explore the stability and reaction mechanisms of synthesized one-dimensional transition metal dithiolene wire (TM-DWs, TM = Cr – Cu, Rh, Ir, Pt, Pd) for the ORR and the OER in acid solution by density functional theory (DFT) calculations. Our calculations reveal that Co-DW intrinsically exhibits high catalytic activity for bi-functional ORR/OER with low limiting overpotentials (η) of 0.46/0.45 V via four-electron reactions. These low limiting overpotentials arise from modified scaling relations by strengthening the binding free energy of OOH* compared to OH* on TM-DWs, yielding universal minimum ORR/OER overpotentials of η = 0.28/0.22 V, remarkably decreased compared to both metal and oxide surfaces (ηideal = 0.37 V). By applying uni-axial strain, the adsorption strength of reaction intermediates on TM reactive sites can be optimized due to shifts in d-band centers. Our findings provide valuable insight into rational design of non-precious metals based electrocatalysts, and demonstrate a new strategy of tuning adsorptions via uni-axial strain to develop efficient bifunctional electrocatalysts of ORR/OER under optimal conditions.

Original languageEnglish
Pages (from-to)140-148
Number of pages9
JournalJournal of Catalysis
Volume393
DOIs
Publication statusPublished - Jan 2021

Keywords

  • Bifunctional ORR/OER Catalyst
  • Computational screening
  • Density functional theory
  • Oxygen evolution reaction
  • Oxygen reduction reaction
  • Single-atom catalysts

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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