1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea

Shaaban K. Mohamed; Abdel Aal M Jaber; Sohail Saeed; Khuram Shahzad Ahmad; Wing Tak Wong

doi:10.1107/S1600536812018806

1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea

Shaaban K. Mohamed, Abdel Aal M Jaber, Sohail Saeed, Khuram Shahzad Ahmad, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

5 Citations (Scopus)

Abstract

In the title molecule, C18H20F2N 2O2S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N - H⋯O hydrogen bond occurs. In the crystal, N - H⋯O and O - H⋯S hydrogen bonds connect the molecules into chains running diagonally across the bc plane. C - H⋯S and C - H⋯F contacts are also observed.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	6
DOIs	https://doi.org/10.1107/S1600536812018806
Publication status	Published - 1 Jun 2012
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Materials Science(all)
Chemistry(all)

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10.1107/S1600536812018806

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title = "1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea",

abstract = "In the title molecule, C18H20F2N 2O2S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) {\AA}, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N - H⋯O hydrogen bond occurs. In the crystal, N - H⋯O and O - H⋯S hydrogen bonds connect the molecules into chains running diagonally across the bc plane. C - H⋯S and C - H⋯F contacts are also observed.",

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T1 - 1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea

AU - Mohamed, Shaaban K.

AU - Jaber, Abdel Aal M

AU - Saeed, Sohail

AU - Ahmad, Khuram Shahzad

AU - Wong, Wing Tak

PY - 2012/6/1

Y1 - 2012/6/1

N2 - In the title molecule, C18H20F2N 2O2S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N - H⋯O hydrogen bond occurs. In the crystal, N - H⋯O and O - H⋯S hydrogen bonds connect the molecules into chains running diagonally across the bc plane. C - H⋯S and C - H⋯F contacts are also observed.

AB - In the title molecule, C18H20F2N 2O2S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N - H⋯O hydrogen bond occurs. In the crystal, N - H⋯O and O - H⋯S hydrogen bonds connect the molecules into chains running diagonally across the bc plane. C - H⋯S and C - H⋯F contacts are also observed.

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U2 - 10.1107/S1600536812018806

DO - 10.1107/S1600536812018806

M3 - Journal article

SN - 1600-5368

VL - 68

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea

Abstract

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